A 59.4 g sample of polystyrene, which has a specific heat capacity of 1.880 J.g ·°C , is put into a calorimeter (see sketch at right) that contains 200.0 g of water. The temperature of the water starts off at 19.0 °C. When the temperature of the water stops changing it's 27.7 °C. The pressure remains constant at 1 atm. Calculate the initial temperature of the polystyrene sample. Be sure your answer is rounded to 2 significant digits.