6l volume of methane gas, ch4, has the same number of atoms as 6.00 l of krypton gas at the same temperature and pressure.
The Avogadro's law can be used to connect the volume of the gas to its number of moles. This law asserts that at the same temperature and pressure, gases with the same molar amount will occupy the same volume. The number of atoms in the two gases must be equal if the number of moles is the same. Accordingly, if Kr and methane both have the same number of particles, their respective volumes would be the same.
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