Which of the following is always positive when a spontaneous process occurs?

a.
Δ
S
s
y
s
t
e
m

b.
Δ
S
s
u
r
r
o
u
n
d
i
n
g
s

c.
Δ
S
u
n
i
v
e
r
s
e

d.
Δ
H
u
n
i
v
e
r
s
e

e.
Δ
H
s
u
r
r
o
u
n
d
i
n
g
s



Answer :

The second law of thermodynamics states that the universe's entropy always rises for all spontaneous reactions (positive).

Is H favorable or unfavorable for the spontaneous process?

negative

The reaction will be spontaneous at low temperatures if -T-S is positive and -H is negative (decreasing the magnitude of the entropy term). The reaction will be spontaneous at high temperatures if H is positive and T is negative (increasing the magnitude of the entropy term).

Of the following, which characterizes a spontaneous process?

Any process that happens spontaneously under specific circumstances and in a specific direction is said to as spontaneous. Without outside assistance, each choice develops on its own.

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