Consider an ideal gas at 27.0 degrees Celsius and 1.00atmosphere pressure. Imagine the molecules to be uniformly spaced,with each molecule at the center of a small cube. What is thelength Lof an edge of each small cube if adjacent cubes touch but don'toverlap?



Answer :

The length of an edge of each small cube is [tex]3.445 * 10^{-9} m[/tex].

It is given to us that -

Temperature of the ideal gas = 27.0 degree Celsius

Atmospheric pressure on the gas = 1.00 atmosphere pressure

Molecules of the gas are uniformly spread

Each molecule at the center of a small cube

We have to find out the length L of an edge of each small cube if adjacent cubes touch but don't overlap.

For solving this problem, we have to make use of the formula of Boltzmann equation for ideal gas, which can be represented as -

[tex]PV = NkT[/tex] ---- (1)

where,

P = Pressure on the gas

V = Volume of the gas

N = Number of molecules of the gas

k = Boltzmann constant

T = Temperature of the gas

According to the given information, we have -

P = 1 atm = 101325 Pa

N = 1

k = [tex]1.38 *10^{-23} J/K[/tex]

T = 27°C = 27°C + 273 = 300K

Now, substituting these values in equation (1), we have

[tex]PV = NkT\\= > 101325 * V = 1 * 1.38 *10^{-23} * 300\\= > V = \frac{414 * 10^{-23}}{101325} \\= > V = 4.0858 * 10^{-26} m^{3}[/tex]------- (2)

We know that the volume of a cube in terms of its length is given as -

[tex]V = L^{3}\\ = > L = V^{1/3}[/tex] ----- (3)

Substituting the value of V from equation (2) in equation (1), we have -

[tex]L = V^{1/3}\\= > L = (4.0858*10^{-26} )^{1/3}\\= > L = 3.445 * 10^{-9} m[/tex]

Therefore, the length of an edge of each small cube is [tex]3.445 * 10^{-9} m[/tex].

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