Answer :

Using the theories of the cell, we got that Scratches and fingerprints on the surface of the cell can decrease the amount of light that reaches the detector is the reason not to leave fingerprints or scratch the sample cells in spectrophotometric measurements.

This instrument depends on a careful usage to measure accurately the concentration in an specific solution. The wavelength can be inaccurate if some procedures were not done during the preparation process.  

When cleaning the cuvette or manipulating it, always use a lint free cloth and make sure that you removed any drops of water that might have fallen into the cuvette.

Hence, the reason  not to leave fingerprints or scratch the sample cells in spectrophotometric measurements is because Scratches and the fingerprints on the surface of the cell can decrease the amount of light that reaches the detector.

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