The structure of DNA determines the structure of proteins because proteins are made by the central dogma process where DNA is the initial component.
In the process of the central dogma, transcription is the process through which the DNA is transcribed into the mRNA. Through the information in the mRNA, proteins are produced by the translation process.
Hence, the structure of proteins as well its function etc are all determined by the DNA whose information is transcribed and translated for the formation of that particular protein.
Each protein formed from the transcription and translation of DNA has a specialized function to perform.
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