1. Ammonia is a colorless gas with a chemical formula of NH3, when it comes in contact with water, it will be transformed into Ammonium ion and it will produce one hydroxide ion, and this is why Ammonia will present a more basic (pH) behavior, the reaction that represents this behavior is:
NH3 + H2O -> NH4+ + OH-
Number 4 is the only one that represents it well
Number 3 has the same reaction but since there is a plus sign instead of an arrow, I consider it wrong.