A 3.743 g sample of a new organic material is combusted in a bomb calorimeter. The temperature of the calorimeter and its contents increase from 23.97 ∘C to 27.16 ∘C.

The heat capacity (calorimeter constant) of the calorimeter is 41.93 kJ/ ∘C, what is the heat of combustion per gram of the material?

heat of combustion: _________ kJ/g