In aqueous solution, 5.2 mg of iron(III) chloride reacts with excess ammonium hydroxide.A. Write and kalance the equation, including phasesB. Is this a limiting reactant problem? Why or why not?C. Calculate the moles of each product that are formedD. Calculate the grams of each product that are formedI already answered part a and b. I need help on part c and d.



Answer :

With a balanced reaction, we can determine the moles of products. The balanced equation will be:

FeCl3 + 3NH4OH → Fe(OH)3 + 3NH4Cl

They says that NH4OH is in excess, so, the limiting reactant will be FeCl3 and we will do all the calculations with this reactant.

We have to calculate the moles of FeCl3, we will use the molar mass:

[tex]\begin{gathered} molFeCl_3=5.2mg\times\frac{1g}{1000mg}\times\frac{1molFeCl_3}{MolarMass,gFeCl_3} \\ molFeCl_3=5.2mg\times\frac{1g}{1,000mg}\times\frac{1molFeCl_3}{162.2gFeCl_3}=3.2\times10^{-5}molFeCl_3 \end{gathered}[/tex]

Now, to calculate the moles of the products we must take into account the product/reactive ratios, for this we are guided by the coefficients that accompany the molecules.

Ratio Fe(OH)3 to FeCl3 = 1/1

Ratio NH4Cl to FeCl3 = 3/1

Moles of each product

Moles of Fe(OH)3

[tex]molFe(OH)_3=3.2\times10^{-5}molFeCl_3\times\frac{1molFe(OH)_3}{1molFeCl_3}=3.2\times10^{-5}molFe(OH)_3[/tex]

Moles of NH4Cl

[tex]molNH_4Cl=3.2\times10^{-5}molFeCl_3\times\frac{3molNH_4Cl}{1molFeCl_3}=9.6\times10^{-5}molNH_4Cl[/tex]

The grams of each product we will find by multiplying the moles by the molar mass. So we have.

g of Fe(OH)3

[tex]\begin{gathered} gFe(OH)_3=3.2\times10^{-5}molFe(OH)_3\times106.87g/molFe(OH)_3 \\ gFe(OH)_3=3.4\times10^{-3}g=3.4mg \end{gathered}[/tex]

g of NH4Cl

[tex]\begin{gathered} gNH_4Cl=molNH_4Cl\times MolarMassNH_4Cl \\ gNH_4Cl=9.6\times10^{-5}molNH_4Cl\times53.491g/molNH_4Cl=5.1\times10^{-3}g=5.1mg \end{gathered}[/tex]