Fluoroacetate occurs naturally in some plants and is highly toxic to mammals and insects. In cells, it is converted to fluorocitrate, which binds tightly and inhibits an enzyme crucial for cellular respiration, causing citrate buildup. To what enzyme does fluorocitrate bind?.

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25-10-2022
Biology

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Fluoroacetate occurs naturally in some plants and is highly toxic to mammals and insects. In cells, it is converted to fluorocitrate, which binds tightly and inhibits an enzyme crucial for cellular respiration, causing citrate buildup. To what enzyme does fluorocitrate bind?.

Answer :

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Qwdog Qwdog · Answer 1 · 2022-11-03T11:19:23-04:00

Fluro citrate bonds which bind tightly and inhibit with the enzyme called aconitase and will cause the problems for cellular respiration.

The Fluro citrate bonds will be converted into fluoro-cis-aconitate which will then converted into 4-hydroxy-trans-aconitate (HTn) which will bonds with the aconitase which causes difficulty in the cellular respiration.

Aconitase are iron-sulfur proteins which catalyze the reversible isomerization of citrate and isocitrate via cis-aconitate. While in mitochondria aconitase is part of the citric acid cycle, in the cytosol aconitase is a trans-regulatory factor that controls iron homeostasis at a post-transcriptional level. The main function of the aconitase is converting the citrate into isocitrate which is very much helpful in the cellular respiration process.

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