Answer :

ΔHdissolution = 27×10⁻⁵

A calorimeter is a device used for heat measurements necessary for calorimetry

Here given data is 4.79g = KBr and are dissolved in 109.00g water and temperature is 21.08°C and according to calorimeter heat of capacity = 1.84 J/°C

We have to calculate enthalpy of dissolution of KBr = ? ΔHdissolution = 27×10⁻⁵

KBr+H₂0→KBr ΔH=?

qreaction = -qcal

1.79×1.84(-2.4) = 0.8936 J

1000 = -0.0008936

4.79+109.00 = 522.11 g

qcal = 522.11 g×1.84(-2.4) = -2305 J

qreaction = -qcal = -2305 J

n(KBr) = 4.79/74.55gmol⁻¹ = 0.0642mol

2305/ 0.0642mol = 0.00002787mol⁻¹

= 27×10⁻⁵

ΔHdissolution = 27×10⁻⁵

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