Substance A has the following properties.
mp at 1 atm: -20. °C bp at 1 atm: 85°C
ΔHfus : 180. J/g ΔHvap : 500. J/g
Csolid : 1.0 J/g?°C C liquid : 2.5 J/g?°C
Cgas : 0.5 J/g?°C
At 1 atm, a 25-g sample of A is heated from 240.° C to 100.°C at a constant rate of 450. J/min.
(c) Perform any other necessary calculations, and draw a curve of temperature vs. time for the entire heating process.



Answer :

A curve of temperature vs. time for the entire heating process.

The sample is heated up to 100.°C, therefore, the heat and time required to heat the sample to its boiling point, the heat and time required to boil the sample, and the heat and time required to heat the sample from its boiling point to 100.°C are needs to be calculated.

i ) Calculating the heat and time required to heat the sample to its boiling point:

Boiling point = 85°C

C(liquid) = 2.5 J/g °C

The heat required up to melting the sample is calculated in the previous parts. Therefore, the heat required to heat the sample from -20°C to 85°C can be calculated as,

Therefore, T f = 85°C  and T i = - 20°C

Plug in the values in the specific heat formula to calculate the heat energy required to heat the sample to its melting point,

q3 = 25 g ×  2.5 J/g °C × [85 - (-20)]°C

     = 25 J/°C ×[85+20]°C

     = 6562.5 J

The total heat energy required for heating the sample from initial temperature to boiling point is:-

q1 + q2 + q3 = 500 J + 4500 J + 6562.5 J

                    = 11562.5 J

The Rate of heating = 450 J/min

450. J = 1 min

   11562.5 J = ? min

11562.5 J × 1min/450 J = 25.69 min

ii) Calculating the heat and time required to boil the sample:

∆H Vap = 500 J/g

The boiling is the phase change from liquid to gas at 85°C, therefore, the heat required to boil the sample can be determined

q4= m × ∆Hvap

    = 25 g × 500 J/g

   = 12500 J

Thus, total heat required to this phase change is q1 + q2 + q3 + q4  = 500 J + 4500 J +6562.5  J + 12500 J = 24062.5 J

The Rate of heating = 450 J / min

450 J = 1 min

24062.5 J = ? min

24062.5J ×  1min / 450 J = 53.47 min

iii) Calculating the heat and time required to heat the sample from its boiling point to 100°C

C gas = 0.5 J / g °C

The heat required to boil the sample is calculated in the previous parts. Therefore, the heat required to heat the sample from 85°C to 100°C can be calculated as,

Therefore, T f = 100.°C  and T i = 85°C

q5 = 25 g ×  0.5 J / g °C × [100 - 85] °C

    = 25 J / °C ×15 °C

    = 187.5  J

The total heat energy required for heating the sample from initial temperature to 100°C is

q1 + q2 + q3 + q4 + q5 = 500 J + 4500 J + 2625J + 12500 J + 187.5 J

                                      =24250 J

The Rate of heating = 450 J / min

  450. J = 1 min

 24250 J=? min

Thus, heating the sample to 100.°C takes a total of 53.89 min.

iv) Draw a curve of temperature vs. time for the entire heating process:-

Temperature °C     Temperature K     Heat energy (J)     Time (min)

 -40 °C                       233                             0                     0

-20 °C                          253                          500                  1.11    

Melting -20 °C             253                        5000                   11.11

85 °C                         358                         11562.5              25.69

Boiling 85 °C             358                           24062.5          53.475              

100  °C                       373                             24250          53.89

Hence, the graph for the result is in the image.

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