A mixture of 3.00 volumes of H₂ and 1.00 volume of N₂ reacts at 344°C to form ammonia. The equilibrium mixture at 110. atm contains 41.49% NH₃ by volume. Calculate Kp for the reaction, assuming that the gases behave ideally.



Answer :

The Kp of the reaction is 1.5*10^-3

The mole fraction of ammonia at equilibrium is 0.4149. Then the paartial pressure of NH3 is

P NH3 = XNH3 * Ptotal

           = 0.4149 * 110atm

           = 45.6 atm

The partial pressure of NH3 at equilibrium (45.6 atm) to 2x, and solve for x:

       2x = 45.6 atm

         x = 22.8 atm

Total pressure is 110 atm.

Solve for Ptotal using the value of x

Ptotal = 110 atm + 2x

         = 110 atm + 2(22.8)

          = 155.6atm

Then the partial pressures of N2 and H2 are

PN2 = 0.25Ptotal' - x

       = 0.25 * 155.6atm - 22.8

       = 16.1 atm

PH2 = 0.75Ptotal' - 3x

       = 0.75 * 155.6atm - 3(22.8atm)

       = 48.3atm

The equation for Kp is

Kp = P^2 NH3 / P N2 P^3H2

Kp = (45.6)^2 / (16.1)(48.3)^3

Kp = 1.15 *10^-3

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https://brainly.com/question/25651917

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