Answer :

The most polar form is made up of the elements phosphorous and fluorine. P-F because P(EN 2.19) and F(3.98) have higher electronegativity differences than N(EN 3.04) and F. (3.98). 

The more polar the disparity, the greater it is.The bond that phosphorous forms with fluorine will be the most polar of all those mentioned because nitrogen is one of the most electronegative elements in the periodic table. Orbitals collide to form bonds, which can be classified as polar or nonpolar depending on their polarity. They are regarded as an ionic and covalent link in accordance with Fajan's rule, which explains the ionic and covalent character in a bond between two atoms. The difference in electronegativity between the two atoms that make up a bond determines its polarity. A nonpolar covalent bond will form between two atoms if their electronegativity is essentially the same.

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