a 9.119 gram sample of an organic compound containing , and is analyzed by combustion analysis and 18.22 grams of and 7.460 grams of are produced. in a separate experiment, the molar mass is found to be 88.11 g/mol. determine the empirical formula and the molecular formula of the organic compound.



Answer :

The empirical formula and the m0lecular formula of the organic compound

is  CH5O3 and C2H10O6

mass % of C = 12/44 × 7.455/9.119 × 100 = 22.2938

mass % of H = 2/18 × 3.053/9.119 × 100 = 3.716

mass % of O = 100 - [ 22.2938+ 3.716]

                      = 73.991

moles of C = 22.2938/12 = 1.33 = 1.33/1.33 = 1

moles of H = 6.6999/1 = 6.66/1.33 = 5

moles of O = 73.991 / 16 = 4.5 = 4.5/1.33 = 3

empirical formula = CH5O3

Molecular formula = (empirical formula)n

n = molar mass/ empirical mass = 88.11/65 = 2

Molecular formula = C2H10O6

The most straightforward whole number ratio of atoms in a compound is its empirical formula. The empirical formula of sulphur monoxide, abbreviated SO, and disulfur dioxide, abbreviated S2O2, are two straightforward examples of this idea. As a result, the empirical formula for sulphur monoxide and disulfur dioxide, two compounds made of sulphur and oxygen, is the same. Their molecular formulae, which represent how many atoms are present in each molecule of a chemical compound, are different.

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